??? ??? ?? ???, ?? ?? ??? ??? ???? ????????? ??
- ??? ???????(Nature Communications)? 5? 8? ??
¡ø ??? ?????(?1??, ??)? ??? ??(????, ???)
??? ??? ?? ???? ?? ?? ??? ???? ??? ???? ‘?????????(Aquaphotocatalysis)’? ??? ?????. ???? ??? ?? ??? ?????? ??? ?????? ??? ????? ?????? ???? ??? ???? ?????.
????? ??????? ???, ????, 2??? ?????? ? ??? ???? ???? ??? ?? ?????. ???? ??? ? ?? ??? ??? ?? ???? ???(covalent inhibitor)?? ???? ??. ? ???? ??? ????? ???(Sulfur(VI)–Fluoride Exchange: SuFEx)? ?????, ??? ??? ??? ??? ??? ? ?? ????? ????.
?? ????? ?????? ???? ???? ?? ???? ??????, ??? ?? ???? ??? ??? ???? ???? ????? ?? ??? ???? ?????? ????? ??? ? ??. ???? ??-????? ??????? ??? ??? ??? ??? ???? ????? ??????? ?? ??? ?????.
??, ???? ???? ??????? ?? ??? ‘????’?? ???? ?????, ?? ???? ???? ??? ???? ??? ??? ?????. ? ??? ???? ????? ?? ????? ???? ????, ??????, ??? ?? ????? ???? ????? ?????*? ?? ? ????, ?? ? ??? ??????? ??? ? ??? ?????.
* ????? ?????: ?? ???? ???(aromaticity)? ????? ??? ????? ?? ???? ???
??? ??? “????? ???? ??? ?? ?? ??? ?? ??? ?? ????? ????? ???? ??? ???? ????. ?????? ????? ???? ??? ?? ?? ?? ?? ????? ??? ??? ? ?, ????(Biomimicry)? ??? ????? ??? ??? ??”??? ???.
??? “??? ????? 2??? ??????, ???? ??? ???? ? ??? ?? ? ??????? ?? ??? ?”??? ???.
???? ?? ????? ??? ??? ???? ??? ???????(Nature Communications)? 5? 8? ?????.
¡ù ????: “On-Water” Accelerated Dearomative Cycloaddition via Aquaphotocatalysis
¡ù ??: Nature Communications
¡ù
??
